水泥和固化剂加固淤泥的抗硫酸盐侵蚀性对比研究
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Comparative study on resistance to sulfate attack of sludge stabilized with cement and solidifier
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    摘要:

    针对现有研究多集中于水泥加固土抗硫酸盐侵蚀性能,而对新型固化剂材料加固土关注不足的问题,进行了两种材料加固土的抗侵蚀性能对比试验研究。采用不同硫酸盐浓度与两种侵蚀方式,对不同侵蚀龄期下两种加固土进行了系统测试,通过观察表观形貌、测定无侧限抗压强度、计算耐蚀系数,并结合扫描电子显微镜(scanning electron microscope,SEM)微观结构分析,综合揭示了其性能演变规律与侵蚀破坏机制。结果表明:低浓度硫酸盐(≤3 000 mg/L)对两者影响较小,性能降幅均小于20%;而高浓度(≥8 000 mg/L)侵蚀下,水泥土迅速劣化,并随龄期加剧,无侧限抗压强度最大下降100%,耐蚀系数最低降至0。相比之下,固化土的抗侵蚀性能更优,其在半浸泡长期作用下耐蚀系数最低仅为 0.49。固化土抗侵蚀性能整体优于水泥土,主要原因是固化土内部铝相水化产物含量较低,有效抑制了后期膨胀性产物二次钙矾石的生成。

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    To address the issue that most existing studies mainly focus on the sulfate attack resistance of cement-stabilized soil,while insufficient attention has been paid to soil reinforced by new curing agents,this paper conducts a comparative experimental study on the sulfate erosion resistance of soil stabilized with the two materials.With different sulfate concentrations and two erosion modes adopted,systematic tests are carried out on the two stabilized soils at different erosion ages.By observing surface morphology,testing unconfined compressive strength,calculating the sulfate resistance coefficient,and analyzing microstructure via scanning electron microscopy (SEM),the performance evolution law and erosion failure mechanism are comprehensively revealed.The results show that low sulfate concentrations (≤3,000 mg/L) have little effect on both types of stabilized soil,with performance degradation rates all less than 20%.Under high-concentration sulfate erosion (≥8,000 mg/L),cement-stabilized soil deteriorates rapidly,and the degradation intensifies with erosion age,its unconfined compressive strength decreases by up to 100%,and the sulfate resistance coefficient drops to a minimum of 0.In comparison,stabilized soil presents superior erosion resistance,with its minimum corrosion resistance coefficient reaching only 0.49 under long-term semi-immersion conditions.Stabilized soil overall outperforms cement soil in erosion resistance.This is mainly attributed to the lower content of aluminum-phase hydration products inside stabilized soil,which effectively inhibits the formation of expansive secondary ettringite in the later stage.

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于帅帅,魏芳海,王梓奥,等.水泥和固化剂加固淤泥的抗硫酸盐侵蚀性对比研究[J].水运工程,2026(7):190-197.

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  • 在线发布日期: 2026-07-17
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